Hi el mysterioso,
There are several possible reasons for a duplicate table, column or key error:
If you had previously restored your database, ensure it was restored into a completely empty database. Otherwise there will be duplicate data.
Never use your browser’s Back button during an upgrade, as that can cause actions to run twice.
Your server’s PHP max_execution_time may be set too low, forcing the upgrade script to end prematurely. Check with your host about increasing this value from the typical default of 30 seconds.
If you’re using Firefox to perform the upgrade, try using Chrome or Safari instead. In some cases Firefox can re-send requests following a server error, effectively preventing the error from being seen.
Can you try upgrading to EE1.7.1 first and then perform the upgrade to EE21.3?